Gross thermodynamics of two-component core convection     

David Gubbins  Dario Alfè  Guy Masters  G. David Price  Michael Gillan 《Geophysical Journal International》2004,157(3):1407-1414

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External controls on the distribution,fabrics and mineralization of modern microbial mats in a coastal hypersaline lagoon,Cayo Coco (Cuba)   总被引：1，自引：0，他引：1       下载免费PDF全文

Anthony Bouton  Emmanuelle Vennin  Aurélie Pace  Raphaël Bourillot  Christophe Dupraz  Christophe Thomazo  Arnaud Brayard  Guy Désaubliaux  Pieter T. Visscher 《Sedimentology》2016,63(4):972-1016

Active, carbonate‐mineralizing microbial mats flourish in a tropical, highly evaporative, marine‐fed lagoonal network to the south of Cayo Coco Island (Cuba). Hypersaline conditions support the development of a complex sedimentary microbial ecosystem with diverse morphologies, a variable intensity of mineralization and a potential for preservation. In this study, the role of intrinsic (i.e. microbial) and extrinsic (i.e. physicochemical) controls on microbial mat development, mineralization and preservation was investigated. The network consists of lagoons, forming in the interdune depressions of a Pleistocene aeolian substratum; they developed due to a progressive increase in sea‐level since the Holocene. The hydrological budget in the Cayo Coco lagoonal network changes from west to east, increasing the salinity. This change progressively excludes grazers and increases the saturation index of carbonate minerals, favouring the development and mineralization of microbial mats in the easternmost lagoons. Detailed mapping of the easternmost lagoon shows four zones with different flooding regimes. The microbial activity in the mats was recorded using light–dark shifts in conjunction with microelectrode O₂ and HS^? profiles. High rates of O₂ production and consumption, in addition to substantial amounts of exopolymeric substances, are indicative of a potentially strong intrinsic control on mineralization. Seasonal, climate‐driven water fluctuations are key for mat development, mineralization, morphology and distribution. Microbial mats show no mineralization in the permanently submersed zone, and moderate mineralization in zones with alternating immersion and exposure. It is suggested that mineralization is also driven by water‐level fluctuations and evaporation. Mineralized mats are laminated and consist of alternating trapping and binding of grains and microbially induced magnesium calcite and dolomite precipitation. The macrofabrics of the mats evolve from early colonizing Flat mats to complex Cerebroid or Terrace structures. The macrofabrics are influenced by the hydrodynamic regime: wind‐driven waves inducing relief terraces in windward areas and flat morphologies on the leeward side of the lagoon. Other external drivers include: (i) storm events that either promote (for example, by bioclasts covering) or prevent (for example, by causing erosion) microbial mat preservation; and (ii) subsurface degassing, through mangrove roots and desiccation cracks covered by Flat mats (i.e. forming Hemispheroids and Cerebroidal structures). These findings provide in‐depth insights into understanding fossil microbialite morphologies that formed in lagoonal settings.  相似文献   

Stratigraphic modelling of platform architecture and carbonate production: a Messinian case study (Sorbas Basin,SE Spain)          下载免费PDF全文

Christophe Kolodka  Emmanuelle Vennin  Raphael Bourillot  Didier Granjeon  Guy Desaubliaux 《Basin Research》2016,28(5):658-684

The late Messinian mixed carbonate‐siliciclastic platforms of the Sorbas Basin, known as the Terminal Carbonate Complex, record significant changes in carbonate production and geometry. Their facies and stratigraphic architecture result from complex interactions between base‐level fluctuations, evaporite deformation/dissolution and detrital inputs. A 3D quantitative approach (with DIONISOS software) is used to explore the basin‐scale platform architecture and to quantify the carbonate production of the Terminal Carbonate Complex. The modelling strategy consists in integrating detailed 2D field‐based transects and modern carbonate system parameters (e.g. carbonate production rates, bathymetric and hydrodynamic ranges of production). This approach limits user impact and so provides more objective output results. Tests are carried out on carbonate production rates, subsidence and evaporite deformation/dissolution. Numerical modelling provides accurate predictions of geometries, facies distributions and depositional sequence thicknesses, validated by field data. Comparative statistical testing of the field transects and of the various model outputs are used to discern the relative contribution of the parameters tested to the evolution of basin filling. The 3D visualization and quantification of the main carbonate producers (ooids and microbialites) are discussed in terms of changes in base‐level and detrital supply. This study demonstrates that base‐level fluctuations have the greatest impact on the carbonate budget. Evaporite deformation/dissolution affects the type and amount of carbonate production, inducing a transition from an ooid‐ to microbialite‐dominated system and also has a major effect on stratigraphic architecture by inducing the migration of depocentres. The numerical modelling results obtained using modern carbonate system parameters could also be applied to subsurface ooid‐microbialite reservoirs, and the Terminal Carbonate Complex is a good analogue for such systems.  相似文献   

A review of jet grouting practice and development     

Pierre Guy Atangana Njock  Jun Chen  Giuseppe Modoni  Arul Arulrajah  Yong-Hyun Kim 《Arabian Journal of Geosciences》2018,11(16):459

The jet grouting technique was originally initiated in the UK and progressively developed following the needs for larger geometries, ease of implementation, economic rationality, and better mechanical properties. This paper presents a comprehensive review of the development and practice of jet grouting through some fundamental concepts and relevant case studies. Subsequently, a laboratory testing program is performed to investigate the factors affecting the efficacy of the twin grouting system. The principal objective of this study is to define the suitable conditions for the jet grouting efficacy regarding economic rationality as well as quality control. For the first phase, a particular emphasis is placed on the properties of jet columns, site geological conditions, implementation methods, and the justification of each selected treatment option, while the second phase mainly focuses on the unconfined compressive strength (UCS) tests. It follows that the mono-fluid jet grouting system presents a valuable flexibility in dealing with complex configurations; yet, the double- and triple-fluid systems are more indicated for cases of mass treatments for which large portions of space must be treated and overlapping is fundamentally important for the reliability of the treatment. Furthermore, it was established that the efficacy of the twin-jet method primarily relies on the proper adequacy of some critical parameters, namely, the cement content, the water-cement ratio, and cement slurry-water glass ratio. In spite of some uncertainties inherently related to the technique, the UCS test represents the quintessential laboratory index for evaluating the mechanical properties of grouted elements, deriving jet grouting efficacy and the economics of jet grouts.  相似文献   

Assessing the potential of reservoir outflow management to reduce sedimentation using continuous turbidity monitoring and reservoir modelling     

Casey Lee  Guy Foster 《水文研究》2013,27(10):1426-1439

In‐stream sensors are increasingly deployed as part of ambient water quality‐monitoring networks. Temporally dense data from these networks can be used to better understand the transport of constituents through streams, lakes or reservoirs. Data from existing, continuously recording in‐stream flow and water quality monitoring stations were coupled with the two‐dimensional hydrodynamic CE‐QUAL‐W2 model to assess the potential of altered reservoir outflow management to reduce sediment trapping in John Redmond Reservoir, located in east‐central Kansas. Monitoring stations upstream and downstream from the reservoir were used to estimate 5.6 million metric tons of sediment transported to John Redmond Reservoir from 2007 through 2010, 88% of which was trapped within the reservoir. The two‐dimensional model was used to estimate the residence time of 55 equal‐volume releases from the reservoir; sediment trapping for these releases varied from 48% to 97%. Smaller trapping efficiencies were observed when the reservoir was maintained near the normal operating capacity (relative to higher flood pool levels) and when average residence times were relatively short. An idealized, alternative outflow management scenario was constructed, which minimized reservoir elevations and the length of time water was in the reservoir, while continuing to meet downstream flood control end points identified in the reservoir water control manual. The alternative scenario is projected to reduce sediment trapping in the reservoir by approximately 3%, preventing approximately 45 000 metric tons of sediment from being deposited within the reservoir annually. This article presents an approach to quantify the potential of reservoir management using existing in‐stream data; actual management decisions need to consider the effects on other reservoir benefits, such as downstream flood control and aquatic life. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

27Al, 29Si,and 23Na MAS NMR study of an Al,Si ordered alkali feldspar solid solution series     

Brian L. Phillips  R. James Kirkpatrick  Guy L. Hovis 《Physics and Chemistry of Minerals》1988,16(3):262-275

Solid-state ²⁷Al, ²⁹Si and ²³Na MAS NMR spectra have been obtained for an Al,Si ordered low albite to low microcline ion exchange series for which unit-cell parameters and ²⁹Si NMR data have previously been reported. ²⁷Al δ_i vary continuously with composition from 63.4 (±0.5) ppm for albite to 58.9 (±0.5) ppm for microcline, and parallel the ²⁹Si chemical shifts assigned to the T2m-site. The ²⁷Al and ²⁹Si chemical shifts for this series correlate well with composition-dependent lattice parameters, most notably cell volume and the angle [201]¹b. The linewidths of the ²⁹Si and ²⁷Al resonances indicate a significant amount of structural disorder in the intermediate compositions due to Na, K substitution. The 1 σ width of the distribution of average Si-O-T angles for each T-site is estimated to be about 1° for the Or33 sample. The average ²³Na δ_i varies monotonically from -8.5 (±1) ppm for albite to -24.3 (±1)ppm for Or83. Similarly, the average ²³Na nuclear quadrupole coupling constant decreases from 2.60 to 1.15 (±0.05) MHz and the asymmetry parameter of the electric field gradient increases from 0.25 to 0.6 with increasing K-content from albite to Or83. The observed variations in the quadrupole coupling parameters are consistent with simple electrostatic calculations. Higher resolution ²³Na spectra of the intermediate compositions obtained at 11.7 T indicate the presence of an inhomogeneous linebroadening which is related to the distribution of Na-environments. A model based on a random distribution of local compositions does not simulate the spectra, suggesting that the distribution of Na is skewed toward Na-rich clusters. Observation of the ²³Na NMR lineshape of Or49 after short periods of heat treatment indicate that ²³Na NMR is very sensitive to the changes in the Na, K distribution accompanying the early stages of exsolution. Reversible changes occur after heating at 530° C for 3 h, whereas heating at 600° C produces no changes, possibly bracketing the position of the coherent spinodal for Al, Si ordered alkali feldspars at this composition.  相似文献   

Multisite surface reaction versus transport control during the hydrolysis of a complex oxide     

Christophe Guy  Jacques Schott 《Chemical Geology》1989,78(3-4):181-204

Dissolution experiments of a tholeiite basalt glass carried out at different pH and T (up to 300°C) using a rotatingdisc apparatus show that, depending on pH and T, dissolution can be controlled by one of the following steps: (1) surface reaction; (2) transport of reactants in solution; and (3) mixed reaction. The activation energies of these different processes were found to be 60, 9 and 15–50 kJ mol⁻¹, respectively. Taking account of these results, it appears likely that surface reactions are not rate limiting for the hydrolysis of most crystalline silicate minerals in hydrothermal and metamorphic processes, and that caution should be exercised when predicting rate of reactions at high temperatures solely on the basis of activation energies measured at low temperatures.

Comparison of experimental and theoretical potentiometric titrations of the basalt glass and its constituent oxides indicates that the adsorption of H⁺ and OH⁻ ions at the basalt surface is metal cation specific and that the net adsorption can be predicted from the sole knowledge of the acidity constants of the network-forming constituent oxides. We found that in the acidic pH region dissolution is promoted by the adsorption of H⁺ on al and Fe surface sites while in the basic region, dissolution is promoted by the adsorption of OH⁻ on Si sites. The combination of the two distinct types of surface sites, Al and Fe on the one hand, and Si on the other hand, results in a dissolution rate minimum at a pH-value between the pH_zpc of the two groups of oxide components. Linear regressions with a slope n=3.8 are observed both in acid and alkaline solutions in logarithmic plots of the rate of dissolution vs. the surface charge. The value of n, which represents the number of protonation or hydroxylation steps prior to metal detachment, has been found equal to the mean valence of the network-forming metals.

Combining concepts of surface coordination chemistry with transition state theory afforded characterisation of the activated complexes involved in basalt dissolution processes. From the values obtained for the thermodynamic properties of activation for basalt dissolution it is assumed that the activated complexes formed during the H₂O-promoted dissolution of the basalt glass are more tightly bonded than those formed during H⁺- or OH⁻-promoted dissolution.  相似文献   

Structure and subduction processes along the Oregon-Washington margin     

Guy R. Cochrane  Brian T. R. Lewis  Kevin J. McClain 《Pure and Applied Geophysics》1988,128(3-4):767-800

Seismic reflection and refraction data off Washington and Oregon are used to determine the style of sediment deformation and to infer the physical properties of accreted sediments on the lower slope. Onshore-offshore seismic refraction data off Washington are used to determine the location of the trench, or where the plate bending starts.We find that off Washington the subduction zone is characterized by a trench whose physiographic expression is buried under several kilometers of sediments and is tens of kilometers landward of the lower slope, which is accreting seaward as the result of the offscraping of sediments.Seismic reflection data support previous observations that offscraping occurs along seaward and landward dipping thrust faults. Refraction data indicate that a sediment package thrust up along a seaward dipping fault (off Washington) was not measurably changed in velocity with respect to a Cascadia basin section. However a package uplifted by thrusting along a landward dipping fault (off Oregon) did have increased velocity. It is suggested that the increased velocities off Oregon could be the result of erosion and exposure of more deeply buried and compacted sediments, rather than the result of dewatering due to tectonic stress. Off Washington the sensitivity of velocity to porosity and resolution of the seismic method does not preclude dewatering due to tectonic stress, but it does limit the degree of dewatering.In the deeper parts of the lower slope section off Washington and Oregon velocities as high as 3 to 4 km/sec are found. Heat flow data indicate that the temperatures in this high velocity regime are greater than 100°C. It is hypothesized that lithification related to clay diagenesis may be partly responsible for the high velocities, rather than simply compaction. It also appears that the high velocity sediments are subducted while the unlithified low velocity sediments are offscraped.  相似文献   

Geochemical comparison between minettes and kersantites from the Western European Hercynian orogen: trace element and PbSrNd isotope constraints on their origin     

Laurent Turpin  Danielle Velde  Guy Pinte   《Earth and Planetary Science Letters》1988,87(1-2)

Trace element and isotopic characteristics of late Carboniferous to early Permian minettes and kersantites have been determined. These lamprophyres have been sampled throughout the Western European Hercynian orogen, from Brittany to the west to Schwarzwald to the east. In spite of sharp petrological differences reflected by mineralogy and major element geochemistry, minettes and kersantites exhibit close identity with respect to trace element and isotopic features. These features comprise enrichment in incompatible elements, highCs/Rb and lowCe/Pb ratios, Ta and Ti relative depletion, high abundance in transition elements and highNi/Mg ratios. Pb isotope ratios are undistinguishable from those measured on Hercynian continental crust. Initial¹⁴³Nd/¹⁴⁴Nd ratios are between0.5120 (ε_i −5) and0.5122 (ε_i −1) for minettes and kersantites whereas initial⁸⁷Sr/⁸⁶Sr ratios vary between 0.7055–0.710 for minettes and 0.707–0.708 for kersantites. No simple mixing relations are visible on RbSr and SmNd isochron diagrams. The exceptional homogeneity of these geochemical characteristics along a 1000 km traverse does not allow for an hypothesis of enrichment through upper level assimilation and thus leads to propose that these rocks originated through melting of a mantle enriched by recycling of crustal material.  相似文献   

3-D velocity structure of the San Jacinto fault zone near Anza, California—I. P waves     

Jennifer S. Scott  T. Guy Masters  Frank L. Vernon 《Geophysical Journal International》1994,119(2):611-626

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